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| Rank | Player | First Opponent | Opponent | Second Opponent | Opponent |
| 1 | Justin Verlander | Luis Mendoza | KC | ||
| 2 | Cliff Lee | James McDonald | PIT | ||
| 3 | Clayton Kershaw | Matt Harvey | @NYM | ||
| 4 | David Price | Phil Hughes | NYY | Jose Quintana | @CHW |
| 5 | Felix Hernandez | Brad Peacock | @HOU | Joe Blanton | LAA |
| 6 | Stephen Strasburg | Jaime Garcia | STL | ||
| 7 | Matt Cain | Patrick Corbin | ARI | ||
| 8 | Adam Wainwright | Ross Detwiler | @WAS | ||
| 9 | Yu Darvish | Tommy Hanson | @LAA | ||
| 10 | Madison Bumgarner | Ian Kennedy | ARI | ||
| 11 | Matt Harvey | Clayton Kershaw | LAD | ||
| 12 | Cole Hamels | Jeff Locke | PIT | Jon Niese | @NYM |
| 13 | CC Sabathia | Matt Moore | @TB | J.A. Happ | TOR |
| 14 | Mat Latos | Jeff Samardzija | CHC | ||
| 15 | Jake Peavy | Jeremy Hellickson | TB | ||
| 16 | Kris Medlen | Rick Porcello | @DET | ||
| 17 | James Shields | Anibal Sanchez | @DET | ||
| 18 | Matt Moore | CC Sabathia | NYY | Dylan Axelrod | @CHW |
| 19 | Yovani Gallardo | Tyson Ross | @SD | Ted Lilly | @LAD |
| 20 | Jordan Zimmermann | Homer Bailey | CIN | ||
| 21 | Gio Gonzalez | Bronson Arroyo | CIN | ||
| 22 | Jon Lester | Dan Straily | OAK | ||
| 23 | Derek Holland | Joe Blanton | @LAA | Scott Diamond | @MIN |
| 24 | Anibal Sanchez | James Shields | KC | ||
| 25 | Ricky Nolasco | Kevin Correia | @MIN | Carlos Villanueva | CHC |
| 26 | Clay Buchholz | Philip Humber | HOU | ||
| 27 | Jose Fernandez | Mike Pelfrey | @MIN | ||
| 28 | Jeff Samardzija | Mat Latos | @CIN | ||
| 29 | R.A. Dickey | Miguel Gonzalez | @BAL | Phil Hughes | @NYY |
| 30 | Jarrod Parker | Jason Hammel | BAL | ||
| 31 | C.J. Wilson | Aaron Harang | @SEA | ||
| 32 | Chris Sale | Brett Myers | CLE | ||
| 33 | Hiroki Kuroda | Mark Buehrle | TOR | ||
| 34 | Marco Estrada | Edinson Volquez | @SD | ||
| 35 | Alexi Ogando | Jason Vargas | @LAA | Kevin Correia | @MIN |
| 36 | Hisashi Iwakuma | Bud Norris | @HOU | Jason Vargas | LAA |
| 37 | Kyle Lohse | Jason Marquis | @SD | Stephen Fife | @LAD |
| 38 | Mike Minor | Jeff Francis | @COL | Max Scherzer | @DET |
| 39 | Max Scherzer | Wade Davis | KC | Mike Minor | ATL |
| 40 | Justin Masterson | Dylan Axelrod | @CHW | Wade Davis | @KC |
| 41 | Ryan Vogelsong | Wade Miley | ARI | Jason Marquis | @SD |
| 42 | Shelby Miller | Dan Haren | @WAS | Jeff Locke | PIT |
| 43 | Ian Kennedy | Madison Bumgarner | @SF | ||
| 44 | Doug Fister | Paul Maholm | ATL | ||
| 45 | Alex Cobb | Andy Pettitte | NYY | ||
| 46 | Hyun-Jin Ryu | Jeremy Hefner | @NYM | ||
| 47 | Roy Halladay | Wandy Rodriguez | PIT | ||
| 48 | Tim Lincecum | Clayton Richard | @SD | ||
| 49 | Jason Hammel | Jarrod Parker | @OAK | ||
| 50 | Trevor Cahill | Jorge de la Rosa | COL | ||
| 51 | Edwin Jackson | Kevin Slowey | @MIA | ||
| 52 | Tim Hudson | Jhoulys Chacin | @COL | ||
| 53 | Jeremy Hellickson | Jake Peavy | @CHW | ||
| 54 | Paul Maholm | Doug Fister | @DET | ||
| 55 | Jaime Garcia | Stephen Strasburg | @WAS | ||
| 56 | Bud Norris | Hisashi Iwakuma | SEA | Alfredo Aceves | @BOS |
| 57 | Josh Johnson | Ivan Nova | @NYY | ||
| 58 | Homer Bailey | Jordan Zimmermann | @WAS | ||
| 59 | Dillon Gee | Kyle Kendrick | PHI | ||
| 60 | Ryan Dempster | Erik Bedard | HOU | ||
| 61 | Lance Lynn | Jonathan Sanchez | PIT | ||
| 62 | Jon Niese | Ted Lilly | LAD | Cole Hamels | PHI |
| 63 | A.J. Burnett | Jake Westbrook | @STL | ||
| 64 | Josh Beckett | Wily Peralta | MIL | ||
| 65 | Andy Pettitte | Alex Cobb | @TB | ||
| 66 | Wei-Yin Chen | Tommy Milone | @OAK | ||
| 67 | James McDonald | Cliff Lee | @PHI | ||
| 68 | Carlos Villanueva | Tony Cingrani | @CIN | Ricky Nolasco | @MIA |
| 69 | Tommy Milone | Wei-Yin Chen | BAL | ||
| 70 | A.J. Griffin | Felix Doubront | @BOS | Jake Arrieta | BAL |
| 71 | Wade Davis | Max Scherzer | @DET | Justin Masterson | CLE |
| 72 | Mark Buehrle | Hiroki Kuroda | @NYY | ||
| 73 | Wade Miley | Ryan Vogelsong | @SF | Jeff Francis | COL |
| 74 | Jose Quintana | Zach McAllister | CLE | David Price | TB |
| 75 | Ervin Santana | Scott Kazmir | CLE | ||
| 76 | Dan Straily | Jon Lester | @BOS | ||
| 77 | Jason Vargas | Alexi Ogando | TEX | Hisashi Iwakuma | @SEA |
| 78 | Ross Detwiler | Adam Wainwright | STL | Tony Cingrani | CIN |
| 79 | Bronson Arroyo | Gio Gonzalez | @WAS | ||
| 80 | Zach McAllister | Jose Quintana | @CHW | ||
| 81 | Patrick Corbin | Matt Cain | @SF | Jon Garland | COL |
| 82 | Gavin Floyd | Roberto Hernandez | TB | ||
| 83 | Brandon McCarthy | Juan Nicasio | COL | ||
| 84 | Jake Westbrook | A.J. Burnett | PIT | ||
| 85 | Jeremy Guthrie | Ubaldo Jimenez | CLE | ||
| 86 | Barry Zito | Eric Stults | @SD | ||
| 87 | Wily Peralta | Josh Beckett | @LAD | ||
| 88 | Julio Teheran | Jon Garland | @COL | ||
| 89 | Felix Doubront | A.J. Griffin | OAK | Brad Peacock | HOU |
| 90 | Clayton Richard | Tim Lincecum | SF | ||
| 91 | Wandy Rodriguez | Roy Halladay | @PHI | ||
| 92 | Kevin Correia | Ricky Nolasco | MIA | Alexi Ogando | TEX |
| 93 | Roberto Hernandez | Gavin Floyd | @CHW | ||
| 94 | Vance Worley | Justin Grimm | TEX | ||
| 95 | Rick Porcello | Kris Medlen | ATL | ||
| 96 | Tony Cingrani | Carlos Villanueva | CHC | Ross Detwiler | @WAS |
| 97 | Dan Haren | Shelby Miller | STL | Mike Leake | CIN |
| 98 | Jhoulys Chacin | Tim Hudson | ATL | ||
| 99 | Edinson Volquez | Marco Estrada | MIL | ||
| 100 | Joe Blanton | Derek Holland | TEX | Felix Hernandez | @SEA |
| 101 | Erik Bedard | Ryan Dempster | @BOS | ||
| 102 | Miguel Gonzalez | R.A. Dickey | TOR | ||
| 103 | Tyson Ross | Yovani Gallardo | MIL | ||
| 104 | Phil Hughes | David Price | @TB | R.A. Dickey | TOR |
| 105 | Ivan Nova | Josh Johnson | TOR | ||
| 106 | Kyle Kendrick | Dillon Gee | @NYM | ||
| 107 | Ted Lilly | Jon Niese | @NYM | Yovani Gallardo | MIL |
| 108 | Bartolo Colon | Alfredo Aceves | @BOS | Chris Tillman | BAL |
| 109 | Juan Nicasio | Brandon McCarthy | @ARI | ||
| 110 | Lucas Harrell | Joe Saunders | SEA | ||
| 111 | Travis Wood | Mike Leake | @CIN | Alex Sanabia | @MIA |
| 112 | J.A. Happ | Chris Tillman | @BAL | CC Sabathia | @NYY |
| 113 | Brad Peacock | Felix Hernandez | SEA | Felix Doubront | @BOS |
| 114 | Jonathan Sanchez | Lance Lynn | @STL | ||
| 115 | Jake Arrieta | A.J. Griffin | @OAK | ||
| 116 | Scott Feldman | Wade LeBlanc | @MIA | ||
| 117 | Chris Tillman | J.A. Happ | TOR | Bartolo Colon | @OAK |
| 118 | Nick Tepesch | Pedro Hernandez | @MIN | ||
| 119 | Mike Leake | Travis Wood | CHC | Dan Haren | @WAS |
| 120 | Tommy Hanson | Yu Darvish | TEX | ||
| 121 | Brett Myers | Chris Sale | @CHW | ||
| 122 | Jorge de la Rosa | Trevor Cahill | @ARI | ||
| 123 | Wade LeBlanc | Scott Feldman | CHC | ||
| 124 | Aaron Harang | C.J. Wilson | LAA | ||
| 125 | Brandon Maurer | Garrett Richards | LAA | ||
| 126 | Jason Marquis | Kyle Lohse | MIL | Ryan Vogelsong | SF |
| 127 | Mike Pelfrey | Jose Fernandez | MIA | ||
| 128 | Joe Saunders | Lucas Harrell | @HOU | ||
| 129 | Ubaldo Jimenez | Jeremy Guthrie | @KC | ||
| 130 | Eric Stults | Barry Zito | SF | ||
| 131 | Kevin Slowey | Edwin Jackson | CHC | ||
| 132 | Dylan Axelrod | Justin Masterson | CLE | Matt Moore | TB |
| 133 | Jeremy Hefner | Hyun-Jin Ryu | LAD | ||
| 134 | Jeff Francis | Mike Minor | ATL | Wade Miley | @ARI |
| 135 | Jon Garland | Julio Teheran | ATL | Patrick Corbin | @ARI |
| 136 | Jeff Locke | Cole Hamels | @PHI | Shelby Miller | @STL |
| 137 | Scott Diamond | Derek Holland | TEX | ||
| 138 | Alfredo Aceves | Bartolo Colon | OAK | Bud Norris | HOU |
| 139 | Garrett Richards | Brandon Maurer | @SEA | ||
| 140 | Justin Grimm | Vance Worley | @MIN | ||
| 141 | Luis Mendoza | Justin Verlander | @DET | ||
| 142 | Philip Humber | Clay Buchholz | @BOS | ||
| 143 | Pedro Hernandez | Nick Tepesch | TEX | ||
| 144 | Scott Kazmir | Ervin Santana | @KC | ||
| 145 | Alex Sanabia | Travis Wood | CHC | ||
| 146 | Stephen Fife | Kyle Lohse | MIL |